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N,N-Dimethylformamide-stabilized palladium nanoclusters as a catalyst for Larock indole synthesis

We show that N,N-dimethylformamide-stabilized Pd nanoclusters (NCs) have high catalytic activity in the reaction of substituted 2-iodoanilines with alkynes to give 2,3-disubstituted indoles. This indole synthesis does not require phosphine ligands and proceeds with low Pd catalyst loadings. The Pd N...

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Detalles Bibliográficos
Autores principales: Onishi, Kaito, Oikawa, Kei, Yano, Hiroki, Suzuki, Takeyuki, Obora, Yasushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9079145/
https://www.ncbi.nlm.nih.gov/pubmed/35542799
http://dx.doi.org/10.1039/c8ra01410h