Cargando…

N,N-Dimethylformamide-stabilized palladium nanoclusters as a catalyst for Larock indole synthesis

We show that N,N-dimethylformamide-stabilized Pd nanoclusters (NCs) have high catalytic activity in the reaction of substituted 2-iodoanilines with alkynes to give 2,3-disubstituted indoles. This indole synthesis does not require phosphine ligands and proceeds with low Pd catalyst loadings. The Pd N...

Descripción completa

Detalles Bibliográficos
Autores principales:	Onishi, Kaito, Oikawa, Kei, Yano, Hiroki, Suzuki, Takeyuki, Obora, Yasushi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9079145/ https://www.ncbi.nlm.nih.gov/pubmed/35542799 http://dx.doi.org/10.1039/c8ra01410h

Ejemplares similares

Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
por: Nagata, Tatsuki, et al.
Publicado: (2019)

Synthesis and Characterization of N,N-Dimethylformamide-Protected Palladium Nanoparticles and Their Use in the Suzuki–Miyaura Cross-Coupling Reaction
por: Ishida, Junya, et al.
Publicado: (2020)

N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols
por: Nagata, Tatsuki, et al.
Publicado: (2022)

N,N-Dimethylformamide-Protected Single-Sized Metal Nanoparticles and Their Use as Catalysts for Organic Transformations
por: Nagata, Tatsuki, et al.
Publicado: (2019)

Sequential Sonagashira and Larock Indole Synthesis Reactions in a General Strategy To Prepare Biologically Active β-Carboline-Containing Alkaloids
por: Pan, Xiaohong, et al.
Publicado: (2014)

Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ(2) N (3),S}palladium(II) N,N-dimethylformamide disolvate
por: Khaledi, Hamid, et al.
Publicado: (2010)

Reproductive toxicology. N,N-dimethylformamide.
Publicado: (1997)

Acetoguanamine N,N-dimethylformamide solvate
por: Portalone, Gustavo
Publicado: (2008)

Atomic cerium modulated palladium nanoclusters exsolved ferrite catalysts for lean methane conversion
por: Yang, Yanling, et al.
Publicado: (2022)

Recent Uses of N,N-Dimethylformamide and N,N-Dimethylacetamide as Reagents
por: Le Bras, Jean, et al.
Publicado: (2018)

Bis[benzyl N′-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-κ(2) N′,S]nickel(II) N,N-dimethylformamide disolvate
por: Khaledi, Hamid, et al.
Publicado: (2008)

Occupational Exposure to N,N-Dimethylformamide in the Summer and Winter
por: MIYAUCHI, Hiroyuki, et al.
Publicado: (2014)

Green Synthesis of Fluorescent Palladium Nanoclusters
por: Peng, Yan, et al.
Publicado: (2018)

Isolation and Structures of Polyarene Palladium Nanoclusters
por: Hatano, Ayaka, et al.
Publicado: (2023)

Bis{benzyl N′-[(1H-indol-3-yl)methylene]dithiocarbazato-κ(2) N′,S}copper(II) N,N-dimethylformamide disolvate
por: Khaledi, Hamid, et al.
Publicado: (2009)

cis-Diamminedichloridoplatinum(II) N,N-dimethylformamide monosolvate
por: Johnston, Dean H., et al.
Publicado: (2012)

Palladium(II) Complexes with N-Phosphanyl-N-heterocyclic Carbenes as Catalysts for Intermolecular Alkyne Hydroaminations
por: Franco, Dario, et al.
Publicado: (2018)

Formic Acid as Carbon Monoxide Source in the Palladium-Catalyzed N-Heterocyclization of o-Nitrostyrenes to Indoles
por: Fouad, Manar Ahmed, et al.
Publicado: (2023)

Poly[[μ-(3-aminopyridine)-κ(2) N:N′-μ-chlorido-chlorido(N,N′-dimethylformamide-κO)nickel(II)] N,N′-dimethylformamide monosolvate]
por: Yeh, Chun-Wei, et al.
Publicado: (2012)

1,5-Diphenylcarbonohydrazide N,N-dimethylformamide
por: Zhang, Ai-yun, et al.
Publicado: (2010)

2-Aminoterephthalic acid N,N-dimethylformamide disolvate
por: Loos, Stefan, et al.
Publicado: (2012)

Ultrasonic cavitation in CO(2)-expanded N, N-dimethylformamide (DMF)
por: Gao, Hanyang, et al.
Publicado: (2021)

Extensional Rheology of Poly(vinylidene fluoride)/N,N-dimethylformamide Solutions
por: Xu, Lei, et al.
Publicado: (2023)

N-Heterocyclic Carbene Modified Palladium Catalysts for the Direct Synthesis of Hydrogen Peroxide
por: Lewis, Richard J., et al.
Publicado: (2022)

Synthesis of indolo[1,2-c]quinazolines from 2-alkynylaniline derivatives through Pd-catalyzed indole formation/cyclization with N,N-dimethylformamide dimethyl acetal
por: Arcadi, Antonio, et al.
Publicado: (2018)

Poly[[tris(N,N-dimethylformamide)(μ(4)-5-nitroisophthalato)(μ(3)-5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]
por: Su, Meng, et al.
Publicado: (2010)

Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ(2) N,O}nickel(II) N,N-dimethylformamide disolvate
por: Ali, Hapipah M., et al.
Publicado: (2008)

Palladium-catalyzed dual C–H or N–H functionalization of unfunctionalized indole derivatives with alkenes and arenes
por: Broggini, Gianluigi, et al.
Publicado: (2012)

Dual Effects of N,N-dimethylformamide on Cell Proliferation and Apoptosis in Breast Cancer
por: Zhang, Jihong, et al.
Publicado: (2017)

N,N-dimethylformamide induces cellulase production in the filamentous fungus Trichoderma reesei
por: Chen, Yumeng, et al.
Publicado: (2019)

A Case of Autoimmune Hepatitis after Occupational Exposure to N,N-Dimethylformamide
por: Jang, Boo-ok, et al.
Publicado: (2020)

Tailored Synthesis of Catalytically Active Cerium Oxide for N, N-Dimethylformamide Oxidation
por: Fonzeu Monguen, Cedric Karel, et al.
Publicado: (2023)

Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium
por: Faizi, Md. Serajul Haque, et al.
Publicado: (2015)

N-Heterocyclic carbene–palladium catalysts for the direct arylation of pyrrole derivatives with aryl chlorides
por: Özdemir, Ismail, et al.
Publicado: (2013)

Synthesis of New N-Arylpyrimidin-2-amine Derivatives Using a Palladium Catalyst
por: El-Deeb, Ibrahim Mustafa, et al.
Publicado: (2008)

A Journey from June 2018 to October 2021 with N,N-Dimethylformamide and N,N-Dimethylacetamide as Reactants
por: Muzart, Jacques
Publicado: (2021)

Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates
por: Alexy, Eric J., et al.
Publicado: (2019)

Recent Advances in the Synthesis of 3,n-Fused Tricyclic Indole Skeletons via Palladium-Catalyzed Domino Reactions
por: Fan, Liangxin, et al.
Publicado: (2023)

μ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate
por: Young, Cyril, et al.
Publicado: (2012)

(3,5-Dichlorosalicylaldehyde thiosemicarbazonato-κ(3) S,N (1),O)(N,N′-dimethylformamide-κO)copper(II) dimethylformamide solvate
por: Wang, Yuan, et al.
Publicado: (2008)

Cannot write session to /tmp/vufind_sessions/sess_h7c5fho9hdc3irme7bbpul5bdr