Cargando…

Transfer hydrogenation of aldehydes catalyzed by silyl hydrido iron complexes bearing a [PSiP] pincer ligand

The synthesis and characterization of a series of silyl hydrido iron complexes bearing a pincer-type [PSiP] ligand (2-R(2)PC(6)H(4))(2)SiH(2) (R = Ph (1) and (i)Pr (5)) or (2-Ph(2)PC(6)H(4))(2)SiMeH (2) were reported. Preligand 1 reacted with Fe(PMe(3))(4) to afford complex ((2-Ph(2)PC(6)H(4))SiH)Fe...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Peng, Li, Xiaoyan, Qi, Xinghao, Sun, Hongjian, Fuhr, Olaf, Fenske, Dieter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9079873/
https://www.ncbi.nlm.nih.gov/pubmed/35539322
http://dx.doi.org/10.1039/c8ra02606h