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Room-temperature borylation and one-pot two-step borylation/Suzuki–Miyaura cross-coupling reaction of aryl chlorides

A highly efficient room-temperature borylation strategy of aryl chlorides is described. Utilizing Buchwald's second-generation preformed catalyst, boronate esters were obtained for a wide range of substrates in high yield. The method was also applied to Suzuki–Miyaura cross-coupling reaction in...

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Detalles Bibliográficos
Autores principales: Ji, Hong, Wu, Li-Yang, Cai, Jiang-Hong, Li, Guo-Rong, Gan, Na-Na, Wang, Zhao-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9079898/
https://www.ncbi.nlm.nih.gov/pubmed/35539348
http://dx.doi.org/10.1039/c8ra01381k