The influence of substituent field and resonance effects on the ease of N-heterocyclic carbene formation from imidazolium rings

Using a set of twelve selected substituents, the influence of substituent properties on the ease of deprotonation of imidazolium cations and mesoionic imidazolium-4-olates measured by the CREF index has been investigated. Significant correlations between CREF values and the Swain and Lupton field (F...

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Detalles Bibliográficos
Autores principales: Oziminski, Wojciech P., Ramsden, Christopher A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9079947/
https://www.ncbi.nlm.nih.gov/pubmed/35541359
http://dx.doi.org/10.1039/c8ra02526f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9079947/
https://www.ncbi.nlm.nih.gov/pubmed/35541359
http://dx.doi.org/10.1039/c8ra02526f

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