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One-pot synthesis of chiral alcohols from alkynes by CF(3)SO(3)H/ruthenium tandem catalysis

A practical one-pot synthesis of chiral alcohols from readily available alkynes via tandem catalysis by the combination of CF(3)SO(3)H and a fluorinated chiral diamine Ru(ii) complex in aqueous CF(3)CH(2)OH is described. Very interestingly, the combination of fluorinated catalysts and solvent exhibi...

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Detalles Bibliográficos
Autores principales: Liu, Huan, Liu, Sensheng, Zhou, Haifeng, Liu, Qixing, Wang, Chunqin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9079948/
https://www.ncbi.nlm.nih.gov/pubmed/35541341
http://dx.doi.org/10.1039/c8ra02224k