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Cs(2)CO(3)-promoted defluorination and functionalization of α-CF(3) carbonyl compounds in the presence of N-, O-, and/or S-nucleophiles
A simple, efficient, and mild method for defluorination and functionalization of 3,3,3-trifluoro carbonyl compounds has been developed. In the present method, Cs(2)CO(3) can easily convert α-trifluoromethyl esters, amides, and ketones into β,β-S-, O- and/or N-substituted α,β-unsaturated carbonyl com...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080061/ https://www.ncbi.nlm.nih.gov/pubmed/35542242 http://dx.doi.org/10.1039/c8ra02353k |