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Diasteroselective multi-component assemblies from dynamic covalent imine condensation and metal-coordination chemistry: mechanism and narcissistic stereochemistry self-sorting

Self-assembly of a modified tris(2-pyridylmethyl)amine TPMA ligand, zinc(ii) or cobalt(ii) ions, and amino acids have been used effectively as stereo dynamic optical probes for the determination of the enantiomeric excess of free amino acids either using Electronic or Vibrational Circular Dichroism...

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Detalles Bibliográficos
Autores principales: Badetti, Elena, Carmo dos Santos, Nadia Alessandra, Scaramuzzo, Francesca A., Bravin, Carlo, Wurst, Klaus, Licini, Giulia, Zonta, Cristiano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080712/
https://www.ncbi.nlm.nih.gov/pubmed/35540993
http://dx.doi.org/10.1039/c8ra03989e