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Direct reaction between silicon and methanol over Cu-based catalysts: investigation of active species and regeneration of CuCl catalyst

When a CuCl/Si mixture was pretreated at 200–240 °C in a N(2) atmosphere, trimethoxysilane was predominantly formed in the direct reaction of silicon with methanol. When the pretreatment temperatures were raised to 260–340 °C, tetramethoxysilane was favorably formed. The Cu(x)Si(y)Cl(z) species cata...

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Detalles Bibliográficos
Autores principales: Wang, Aili, Zhang, Mingming, Yin, Hengbo, Liu, Shuxin, Liu, Mengke, Hu, Tongjie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080717/
https://www.ncbi.nlm.nih.gov/pubmed/35539692
http://dx.doi.org/10.1039/c8ra03125h