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A combined experimental and DFT mechanistic study for the unexpected nitrosolysis of N-hydroxymethyldialkylamines in fuming nitric acid
The reaction of dimorpholinomethane in fuming HNO(3) was investigated. Interestingly, the major product was identified as N-nitrosomorpholine and a key intermediate N-hydroxymethylmorpholine was detected during the reaction by (1)H-NMR tracking which indicates that the reaction proceeds via an unexp...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080733/ https://www.ncbi.nlm.nih.gov/pubmed/35539630 http://dx.doi.org/10.1039/c8ra03268h |