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A combined experimental and DFT mechanistic study for the unexpected nitrosolysis of N-hydroxymethyldialkylamines in fuming nitric acid

The reaction of dimorpholinomethane in fuming HNO(3) was investigated. Interestingly, the major product was identified as N-nitrosomorpholine and a key intermediate N-hydroxymethylmorpholine was detected during the reaction by (1)H-NMR tracking which indicates that the reaction proceeds via an unexp...

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Detalles Bibliográficos
Autores principales:	Zhang, Yu, Zou, Po, Han, Yingbin, Geng, Yongliang, Luo, Jun, Zhou, Baojing
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080733/ https://www.ncbi.nlm.nih.gov/pubmed/35539630 http://dx.doi.org/10.1039/c8ra03268h

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