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New synthetic pathway leading to oxospirochlorins

In this work we propose a completely new approach for the synthesis of spirochlorin derivatives based on the use of an imino-keto intermediate formed in situ from 2-amino-5,10,15,20-tetraphenylporphyrins and inverse electron demand Diels–Alder (iEDDA) cycloaddition with 3,6-di-2-pyridyl-1,2,4,5-tetr...

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Detalles Bibliográficos
Autores principales: Śniechowska, Justyna, Paluch, Piotr, Pawlak, Tomasz, Bujacz, Grzegorz D., Danikiewicz, Witold, Potrzebowski, Marek J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080854/
https://www.ncbi.nlm.nih.gov/pubmed/35539919
http://dx.doi.org/10.1039/c8ra02445f