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Transition metal free, late-stage, regiospecific, aromatic fluorination on a preparative scale using a KF/crypt-222 complex

We herein report the development of a convenient, regioselective, aromatic fluorination method of hypervalent iodonium ylides for synthesising fluoro-arenes on a preparative scale. This transition metal free, nucleophilic methodology provides good yields for sterically hindered substrates, irrespect...

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Detalles Bibliográficos
Autores principales: Jakobsson, Jimmy Erik, Riss, Patrick Johannes
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9080924/
https://www.ncbi.nlm.nih.gov/pubmed/35539958
http://dx.doi.org/10.1039/c8ra03757d