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Expanding the synthesizable multisubstituted benzo[b]thiophenes via 6,7-thienobenzynes generated from o-silylaryl triflate-type precursors

Various 2,3-disubstituted 6,7-thienobenzynes have been efficiently generated from the corresponding o-silylaryl triflate-type precursors by activation with fluoride ions. The method has expanded the scope of synthesizable multisubstituted benzothiophenes, including those with various heteroatom subs...

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Detalles Bibliográficos
Autores principales: Yoshida, Suguru, Kuribara, Tomoko, Morita, Takamoto, Matsuzawa, Tsubasa, Morimoto, Kazushi, Kobayashi, Takuya, Hosoya, Takamitsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9081209/
https://www.ncbi.nlm.nih.gov/pubmed/35541723
http://dx.doi.org/10.1039/c8ra04035d