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A model study on the photodecarbonyl reaction of (η(5)-C(5)H(5))M(CO)(2) (M = Co, Rh, Ir)
The group 9 organometallic complexes η(5)-CpM(CO)(2) (M = Co, Rh, and Ir) and Si(CH(3))(3)(H) have been considered as a model system to study their photochemical decarbonyl reactions as well as the Si–H bond activation reactions using the CASSCF and MP2-CAS computational methods. For the cobalt comp...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9082091/ https://www.ncbi.nlm.nih.gov/pubmed/35539200 http://dx.doi.org/10.1039/c8ra03866j |