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A model study on the photodecarbonyl reaction of (η(5)-C(5)H(5))M(CO)(2) (M = Co, Rh, Ir)

The group 9 organometallic complexes η(5)-CpM(CO)(2) (M = Co, Rh, and Ir) and Si(CH(3))(3)(H) have been considered as a model system to study their photochemical decarbonyl reactions as well as the Si–H bond activation reactions using the CASSCF and MP2-CAS computational methods. For the cobalt comp...

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Detalles Bibliográficos
Autores principales:	Zhang, Zheng-Feng, Su, Ming-Der
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9082091/ https://www.ncbi.nlm.nih.gov/pubmed/35539200 http://dx.doi.org/10.1039/c8ra03866j

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