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Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation
Reaction of Mes(2)P(O)Li with (C(6)F(5))(2)BCl gave access to an oxygen-linked germinal intramolecular frustrated Lewis pair Mes(2)P(O)B(C(6)F(5))(2) (1). Compound 1 is stable at room temperature and only decomposes when heated to 90 °C. NMR analysis and theoretical analysis revealed the frustrated...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9082762/ https://www.ncbi.nlm.nih.gov/pubmed/35541977 http://dx.doi.org/10.1039/c8ra05108a |