Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation

Reaction of Mes(2)P(O)Li with (C(6)F(5))(2)BCl gave access to an oxygen-linked germinal intramolecular frustrated Lewis pair Mes(2)P(O)B(C(6)F(5))(2) (1). Compound 1 is stable at room temperature and only decomposes when heated to 90 °C. NMR analysis and theoretical analysis revealed the frustrated...

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Detalles Bibliográficos
Autores principales: Wang, Yiheng, Li, Zhen Hua, Wang, Huadong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9082762/
https://www.ncbi.nlm.nih.gov/pubmed/35541977
http://dx.doi.org/10.1039/c8ra05108a
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author Wang, Yiheng
Li, Zhen Hua
Wang, Huadong
author_facet Wang, Yiheng
Li, Zhen Hua
Wang, Huadong
author_sort Wang, Yiheng
collection PubMed
description Reaction of Mes(2)P(O)Li with (C(6)F(5))(2)BCl gave access to an oxygen-linked germinal intramolecular frustrated Lewis pair Mes(2)P(O)B(C(6)F(5))(2) (1). Compound 1 is stable at room temperature and only decomposes when heated to 90 °C. NMR analysis and theoretical analysis revealed the frustrated nature between the boron and phosphorus centers. Compound 1 shows typical frustrated Lewis pair reactivity when treated with dihydrogen, carbon dioxide, alkyne and alkene. The reaction of 1 with isoprene resulted in selective formation of 3,4-phosphoryl/boryl addition product 8.
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spelling pubmed-90827622022-05-09 Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation Wang, Yiheng Li, Zhen Hua Wang, Huadong RSC Adv Chemistry Reaction of Mes(2)P(O)Li with (C(6)F(5))(2)BCl gave access to an oxygen-linked germinal intramolecular frustrated Lewis pair Mes(2)P(O)B(C(6)F(5))(2) (1). Compound 1 is stable at room temperature and only decomposes when heated to 90 °C. NMR analysis and theoretical analysis revealed the frustrated nature between the boron and phosphorus centers. Compound 1 shows typical frustrated Lewis pair reactivity when treated with dihydrogen, carbon dioxide, alkyne and alkene. The reaction of 1 with isoprene resulted in selective formation of 3,4-phosphoryl/boryl addition product 8. The Royal Society of Chemistry 2018-07-23 /pmc/articles/PMC9082762/ /pubmed/35541977 http://dx.doi.org/10.1039/c8ra05108a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Wang, Yiheng
Li, Zhen Hua
Wang, Huadong
Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation
title Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation
title_full Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation
title_fullStr Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation
title_full_unstemmed Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation
title_short Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation
title_sort synthesis of an oxygen-linked germinal frustrated lewis pair and its application in small molecule activation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9082762/
https://www.ncbi.nlm.nih.gov/pubmed/35541977
http://dx.doi.org/10.1039/c8ra05108a
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AT lizhenhua synthesisofanoxygenlinkedgerminalfrustratedlewispairanditsapplicationinsmallmoleculeactivation
AT wanghuadong synthesisofanoxygenlinkedgerminalfrustratedlewispairanditsapplicationinsmallmoleculeactivation

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