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Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation

Reaction of Mes(2)P(O)Li with (C(6)F(5))(2)BCl gave access to an oxygen-linked germinal intramolecular frustrated Lewis pair Mes(2)P(O)B(C(6)F(5))(2) (1). Compound 1 is stable at room temperature and only decomposes when heated to 90 °C. NMR analysis and theoretical analysis revealed the frustrated...

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Detalles Bibliográficos
Autores principales:	Wang, Yiheng, Li, Zhen Hua, Wang, Huadong
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9082762/ https://www.ncbi.nlm.nih.gov/pubmed/35541977 http://dx.doi.org/10.1039/c8ra05108a

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