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Regio-selective and stereo-selective hydrosilylation of internal alkynes catalyzed by ruthenium complexes

In this study, ruthenium(ii)-catalyzed direct hydrosilylation of internal alkynes with high regio-selectivity and stereo-selectivity is reported. This title transformation led to various vinylsilanes in good to excellent yields. This approach features mild reaction conditions, low catalyst loading,...

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Detalles Bibliográficos
Autores principales: Dai, Wenhao, Wu, Xiaowei, Li, Chunpu, Zhang, Rui, Wang, Jiang, Liu, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9084253/
https://www.ncbi.nlm.nih.gov/pubmed/35542735
http://dx.doi.org/10.1039/c8ra04083d