Novel total syntheses of oxoaporphine alkaloids enabled by mild Cu-catalyzed tandem oxidation/aromatization of 1-Bn-DHIQs

Novel total syntheses of oxoaporphine alkaloids such as liriodenine, dicentrinone, cassameridine, lysicamine, oxoglaucine and O-methylmoschatoline were developed. The key step of these total syntheses is Cu-catalyzed conversion of 1-benzyl-3,4-dihydro-isoquinolines (1-Bn-DHIQs) to 1-benzoyl-isoquino...

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Detalles Bibliográficos
Autores principales: Zheng, Bo, Qu, Hui-Ya, Meng, Tian-Zhuo, Lu, Xia, Zheng, Jie, He, Yun-Gang, Fan, Qi-Qi, Shi, Xiao-Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9084380/
https://www.ncbi.nlm.nih.gov/pubmed/35548004
http://dx.doi.org/10.1039/c8ra05338c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9084380/
https://www.ncbi.nlm.nih.gov/pubmed/35548004
http://dx.doi.org/10.1039/c8ra05338c

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