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Expanding pentafluorouranates: hydrothermal synthesis and characterization of β-NaUF(5) and β-NaUF(5)·H(2)O

Two new sodium uranium(iv) pentafluorides were synthesized from uranium dioxide, HF, and NaF using mild hydrothermal conditions. β-NaUF(5)·H(2)O has greater lattice energy than previously-known α-NaUF(5)·H(2)O and possesses lower symmetry with the latter compound being orthorhombic, whereas β-NaUF(5...

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Detalles Bibliográficos
Autores principales: Chemey, Alexander T., Sperling, Joseph M., Albrecht-Schmitt, Thomas E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9084403/
https://www.ncbi.nlm.nih.gov/pubmed/35548398
http://dx.doi.org/10.1039/c8ra05780j