Rh(iii)-catalyzed synthesis of tetracyclic isoquinolinium salts via C–H activation and [4+2] annulation of 1-phenyl-3,4-dihydroisoquinolines and alkynes in ethanol

An efficient and convenient method to construct tetracyclic isoquinolinium salts via [Cp*RhCl(2)](2) catalyzed C–H activation and [4 + 2] annulation reactions in ethanol is described. This reaction is very fast and highly efficient in the green solvent ethanol. The reaction works with a broad substr...

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Detalles Bibliográficos
Autores principales: Dang, Xinxin, He, Yu, Liu, Yingtian, Chen, Xuehong, Li, Jun-Long, Zhou, Xian-Li, Jiang, Hezhong, Li, Jiahong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9085511/
https://www.ncbi.nlm.nih.gov/pubmed/35547300
http://dx.doi.org/10.1039/c8ra05443f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9085511/
https://www.ncbi.nlm.nih.gov/pubmed/35547300
http://dx.doi.org/10.1039/c8ra05443f

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