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Metal-free hypervalent iodine/TEMPO mediated oxidation of amines and mechanistic insight into the reaction pathways

A highly efficient metal free approach for the oxidation of primary and secondary amines to their corresponding aldehydes and ketones using PhI(OAc)(2) in combination with a catalytic amount of TEMPO as an oxidizing agent is described. This protocol is rapid and provides diverse products under milde...

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Detalles Bibliográficos
Autores principales: Bansode, Ajay H., Suryavanshi, Gurunath
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086218/
https://www.ncbi.nlm.nih.gov/pubmed/35547530
http://dx.doi.org/10.1039/c8ra07451h