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Synthesis of α,β-unsaturated esters of perfluoropolyalkylethers (PFPAEs) based on hexafluoropropylene oxide units for photopolymerization

α,β-unsaturated esters are usually synthesized for polymer applications. However, the addition of maleate (cis-configuration) to a fluorinated moiety is challenging due to its potential isomerization during esterification. Various synthetic routes were attempted and led to very low conversion or sid...

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Detalles Bibliográficos
Autores principales: Bonneaud, Céline, Decostanzi, Mélanie, Burgess, Julia, Trusiano, Giuseppe, Burgess, Trevor, Bongiovanni, Roberta, Joly-Duhamel, Christine, Friesen, Chadron M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086334/
https://www.ncbi.nlm.nih.gov/pubmed/35547709
http://dx.doi.org/10.1039/c8ra06354k