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Spontaneous Water Radical Cation Oxidation at Double Bonds in Microdroplets
Spontaneous oxidation of compounds containing diverse X=Y moieties (e.g., sulfonamides, ketones, esters, sulfones) occurs readily in organic-solvent microdroplets. This surprising phenomenon is proposed to be driven by the generation of an intermediate species [M+H(2)O](+·): a covalent adduct of wat...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Frontiers Media S.A.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9086510/ https://www.ncbi.nlm.nih.gov/pubmed/35559217 http://dx.doi.org/10.3389/fchem.2022.903774 |