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Chemoenzymatic Synthesis of the Most Pleasant Stereoisomer of Jessemal
[Image: see text] We describe the asymmetric synthesis of the most pleasant enantiomer of Jessemal fragrance. The key steps are (i) the one-pot reduction of an α-chloro-tetrasubstituted cyclohexenone to give the chlorohydrin, catalyzed by two stereoselective redox enzymes (an ene-reductase and an al...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9087343/ https://www.ncbi.nlm.nih.gov/pubmed/35442680 http://dx.doi.org/10.1021/acs.joc.2c00427 |