Enantioselective Addition of Remote Alkyl Radicals to Double Bonds by Photocatalytic Proton-Coupled Electron Transfer (PCET) Deconstruction of Unstrained Cycloalkanols

[Image: see text] Herein, we report the enantioselective addition of remote alkyl radicals, generated from the ring opening of unstrained cycloalkanols by a proton-coupled electron transfer (PCET) process, to 2-acyl imidazoles previously coordinated to a rhodium-based chiral Lewis acid. High yields...

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Detalles Bibliográficos
Autores principales: Salaverri, Noelia, Carli, Benedetta, Díaz-Tendero, Sergio, Marzo, Leyre, Alemán, José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9087350/
https://www.ncbi.nlm.nih.gov/pubmed/35362991
http://dx.doi.org/10.1021/acs.orglett.2c00662

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9087350/
https://www.ncbi.nlm.nih.gov/pubmed/35362991
http://dx.doi.org/10.1021/acs.orglett.2c00662

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