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Reactions of [60]fullerene with alkynes promoted by OH(−)
In the current work, the reactions of [60]fullerene with alkynes promoted by OH(−) (base) are addressed. The treatment of C(60) with alkynes in the presence of TBAOH produces alkynylation products (R-C(60)–H) with high selectivity in o-DCB at 100 °C. Plausible reaction mechanisms were proposed. This...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9087709/ https://www.ncbi.nlm.nih.gov/pubmed/35548388 http://dx.doi.org/10.1039/d2ra01300b |