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Reactions of [60]fullerene with alkynes promoted by OH(−)
In the current work, the reactions of [60]fullerene with alkynes promoted by OH(−) (base) are addressed. The treatment of C(60) with alkynes in the presence of TBAOH produces alkynylation products (R-C(60)–H) with high selectivity in o-DCB at 100 °C. Plausible reaction mechanisms were proposed. This...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9087709/ https://www.ncbi.nlm.nih.gov/pubmed/35548388 http://dx.doi.org/10.1039/d2ra01300b |
| _version_ | 1784704222896324608 |
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| author | Chang, Wei-Wei He, Fa-Hui García-Peñas, Alberto Shekh, Mehdihasan I. Li, Zong-Jun |
| author_facet | Chang, Wei-Wei He, Fa-Hui García-Peñas, Alberto Shekh, Mehdihasan I. Li, Zong-Jun |
| author_sort | Chang, Wei-Wei |
| collection | PubMed |
| description | In the current work, the reactions of [60]fullerene with alkynes promoted by OH(−) (base) are addressed. The treatment of C(60) with alkynes in the presence of TBAOH produces alkynylation products (R-C(60)–H) with high selectivity in o-DCB at 100 °C. Plausible reaction mechanisms were proposed. This work provides a convenient and environmental friendly method for the functionalization of fullerenes. |
| format | Online Article Text |
| id | pubmed-9087709 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2022 |
| publisher | The Royal Society of Chemistry |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-90877092022-05-10 Reactions of [60]fullerene with alkynes promoted by OH(−) Chang, Wei-Wei He, Fa-Hui García-Peñas, Alberto Shekh, Mehdihasan I. Li, Zong-Jun RSC Adv Chemistry In the current work, the reactions of [60]fullerene with alkynes promoted by OH(−) (base) are addressed. The treatment of C(60) with alkynes in the presence of TBAOH produces alkynylation products (R-C(60)–H) with high selectivity in o-DCB at 100 °C. Plausible reaction mechanisms were proposed. This work provides a convenient and environmental friendly method for the functionalization of fullerenes. The Royal Society of Chemistry 2022-05-10 /pmc/articles/PMC9087709/ /pubmed/35548388 http://dx.doi.org/10.1039/d2ra01300b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
| spellingShingle | Chemistry Chang, Wei-Wei He, Fa-Hui García-Peñas, Alberto Shekh, Mehdihasan I. Li, Zong-Jun Reactions of [60]fullerene with alkynes promoted by OH(−) |
| title | Reactions of [60]fullerene with alkynes promoted by OH(−) |
| title_full | Reactions of [60]fullerene with alkynes promoted by OH(−) |
| title_fullStr | Reactions of [60]fullerene with alkynes promoted by OH(−) |
| title_full_unstemmed | Reactions of [60]fullerene with alkynes promoted by OH(−) |
| title_short | Reactions of [60]fullerene with alkynes promoted by OH(−) |
| title_sort | reactions of [60]fullerene with alkynes promoted by oh(−) |
| topic | Chemistry |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9087709/ https://www.ncbi.nlm.nih.gov/pubmed/35548388 http://dx.doi.org/10.1039/d2ra01300b |
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