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Stabilization of beryllium-containing planar pentacoordinate carbon species through attaching hydrogen atoms

The diagonal relationship between beryllium and aluminum and the isoelectronic relationship between BeH unit and Al atom were utilized to design nine new planar and quasi-planar pentacoordinate carbon (ppC) species CAl(n)Be(m)H(x)(q) (n + m = 5, q = 0, ±1, x = q + m − 1) (1a–9a) by attaching H atoms...

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Detalles Bibliográficos
Autores principales: Zhao, Xue-Feng, Bian, Jian-Hong, Huang, Fang, Yuan, Caixia, Wang, Qiang, Liu, Ping, Li, Debao, Wang, Xiaotai, Wu, Yan-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9088823/
https://www.ncbi.nlm.nih.gov/pubmed/35558954
http://dx.doi.org/10.1039/c8ra07664b