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High capacity ammonia adsorption in a robust metal–organic framework mediated by reversible host–guest interactions

To understand the exceptional adsorption of ammonia (NH(3)) in MFM-300(Sc) (19.5 mmol g(−1) at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron in...

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Detalles Bibliográficos
Autores principales: Guo, Lixia, Han, Xue, Ma, Yujie, Li, Jiangnan, Lu, Wanpeng, Li, Weiyao, Lee, Daniel, da Silva, Ivan, Cheng, Yongqiang, Rudić, Svemir, Manuel, Pascal, Frogley, Mark D., Ramirez-Cuesta, Anibal J., Schröder, Martin, Yang, Sihai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089318/
https://www.ncbi.nlm.nih.gov/pubmed/35446330
http://dx.doi.org/10.1039/d2cc01197b