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Anionic polycondensation and equilibrium driven monomer formation of cyclic aliphatic carbonates

The current work explores the sodium hydride mediated polycondensation of aliphatic diols with diethyl carbonate to produce both aliphatic polycarbonates and cyclic carbonate monomers. The lengths of the diol dictate the outcome of the reaction; for ethylene glycol and seven other 1,3-diols with a w...

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Detalles Bibliográficos
Autores principales: Hua, Geng, Olsén, Peter, Franzén, Johan, Odelius, Karin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9090641/
https://www.ncbi.nlm.nih.gov/pubmed/35558332
http://dx.doi.org/10.1039/c8ra08219g