Photoinduced nucleophilic substitution of iodocubanes with arylthiolate and diphenylphosphanide ions. Experimental and computational approaches

A new synthetic route to modify the cubane nucleus is reported here. Methyl-4-iodocubane-1-carboxylate (1) and 1,4-diiodocubane (2) were employed as reagents to react with arylthiolate and diphenylphosphanide ions under irradiation in liquid ammonia and dimethylsulphoxide. The reactions proceed to a...

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Detalles Bibliográficos
Autores principales: Jimenez, Liliana B., Puiatti, Marcelo, Andrada, Diego M., Brigante, Federico, Crespo Andrada, Karina F., Rossi, Roberto A., Priefer, Ronny, Pierini, Adriana B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9090936/
https://www.ncbi.nlm.nih.gov/pubmed/35558007
http://dx.doi.org/10.1039/c8ra06275g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9090936/
https://www.ncbi.nlm.nih.gov/pubmed/35558007
http://dx.doi.org/10.1039/c8ra06275g

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