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Selective synthesis of E-vinylsilanes and E,E-divinylsilanes via platinum-catalyzed hydrosilylation of alkynes with secondary silanes
Platinum-N-heterocyclic carbene complex with the formula [Pt(IPr*(OMe))(dvtms)] (where IPr*(OMe) = 1,3-bis{2,6-bis(diphenylmethyl)-4-methoxyphenyl}imidazol-2-ylidene, dvtms = divinyltetramethyldisiloxane) exhibits a high catalytic activity towards the β-E-selective hydrosilylation of terminal acetyl...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9091181/ https://www.ncbi.nlm.nih.gov/pubmed/35558240 http://dx.doi.org/10.1039/c8ra08640k |