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The influence of phosphine ligand substituted [2Fe2S] model complexes as electro-catalyst on proton reduction

To probe the influence of phosphine ligand substitution on the well-known [2Fe2S] model, two new [FeFe]-hydrogenase model complexes with the phosphine ligands, PMe(3) or P(CH(3)O)(3), were synthesized, such as μ-(SCH(CH(2)CH(3))CH(2)S)–Fe(2)(CO)(5)PMe(3)1, and μ-(SCH(CH(2)CH(3))CH(2)S)–Fe(2)(CO)(5)P...

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Detalles Bibliográficos
Autores principales: Zhang, Xia, Ma, Xiaoyuan, Zhang, Tianyong, Li, Bin, Jiang, Shuang, Zhang, Guanghui, Hai, Li, Wang, Jingchao, Shao, Xiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9092242/
https://www.ncbi.nlm.nih.gov/pubmed/35558398
http://dx.doi.org/10.1039/c8ra08016j