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The influence of phosphine ligand substituted [2Fe2S] model complexes as electro-catalyst on proton reduction
To probe the influence of phosphine ligand substitution on the well-known [2Fe2S] model, two new [FeFe]-hydrogenase model complexes with the phosphine ligands, PMe(3) or P(CH(3)O)(3), were synthesized, such as μ-(SCH(CH(2)CH(3))CH(2)S)–Fe(2)(CO)(5)PMe(3)1, and μ-(SCH(CH(2)CH(3))CH(2)S)–Fe(2)(CO)(5)P...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9092242/ https://www.ncbi.nlm.nih.gov/pubmed/35558398 http://dx.doi.org/10.1039/c8ra08016j |