Highly stereoselective spirocyclopropanation of various diazooxindoles with olefins catalyzed using Ru(ii)-complex

Optically active spirocyclopropyloxindole derivatives were efficiently synthesized from diazooxindoles and olefins in the presence of a Ru(ii)-Pheox catalyst. Among a series of Ru(ii)-Pheox catalysts, Ru(ii)-Pheox 6e was determined to be the best catalyst for spirocyclopropanation reactions of diazo...

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Detalles Bibliográficos
Autores principales: Tone, Masaya, Nakagawa, Yoko, Chanthamath, Soda, Fujisawa, Ikuhide, Nakayama, Naofumi, Goto, Hitoshi, Shibatomi, Kazutaka, Iwasa, Seiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9092356/
https://www.ncbi.nlm.nih.gov/pubmed/35558243
http://dx.doi.org/10.1039/c8ra09212e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9092356/
https://www.ncbi.nlm.nih.gov/pubmed/35558243
http://dx.doi.org/10.1039/c8ra09212e

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