Mechanistic Studies on the Synthesis of Pyrrolidines and Piperidines via Copper-Catalyzed Intramolecular C–H Amination

[Image: see text] We have recently developed a method for the synthesis of pyrrolidines and piperidines via intramolecular C–H amination of N-fluoride amides using [Tp(x)CuL] complexes as precatalysts [Tp(x) = tris(pyrazolyl)borate ligand and L = THF or CH(3)CN]. Herein, we report mechanistic studie...

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Detalles Bibliográficos
Autores principales: Muñoz-Molina, José María, Bafaluy, Daniel, Funes-Ardoiz, Ignacio, de Aguirre, Adiran, Maseras, Feliu, Belderrain, Tomás R., Pérez, Pedro J., Muñiz, Kilian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9092462/
https://www.ncbi.nlm.nih.gov/pubmed/35572769
http://dx.doi.org/10.1021/acs.organomet.2c00095

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9092462/
https://www.ncbi.nlm.nih.gov/pubmed/35572769
http://dx.doi.org/10.1021/acs.organomet.2c00095

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