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Site-specific doping of silver atoms into a Au(25) nanocluster as directed by ligand binding preferences

For the first time site-specific doping of silver into a spherical Au(25) nanocluster has been achieved in [Au(19)Ag(6)(MeOPhS)(17)(PPh(3))(6)] (BF(4))(2) (Au(19)Ag(6)) through a dual-ligand coordination strategy. Single crystal X-ray structural analysis shows that the cluster has a distorted center...

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Detalles Bibliográficos
Autores principales: Shi, Wan-Qi, Guan, Zong-Jie, Li, Jiao-Jiao, Han, Xu-Shuang, Wang, Quan-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9093122/
https://www.ncbi.nlm.nih.gov/pubmed/35655555
http://dx.doi.org/10.1039/d2sc00012a