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Site-specific doping of silver atoms into a Au(25) nanocluster as directed by ligand binding preferences
For the first time site-specific doping of silver into a spherical Au(25) nanocluster has been achieved in [Au(19)Ag(6)(MeOPhS)(17)(PPh(3))(6)] (BF(4))(2) (Au(19)Ag(6)) through a dual-ligand coordination strategy. Single crystal X-ray structural analysis shows that the cluster has a distorted center...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9093122/ https://www.ncbi.nlm.nih.gov/pubmed/35655555 http://dx.doi.org/10.1039/d2sc00012a |