The Janus face of high trans-effect carbenes in olefin metathesis: gateway to both productivity and decomposition

Ruthenium–cyclic(alkyl)(amino)carbene (CAAC) catalysts, used at ppm levels, can enable dramatically higher productivities in olefin metathesis than their N-heterocyclic carbene (NHC) predecessors. A key reason is the reduced susceptibility of the metallacyclobutane (MCB) intermediate to decompositio...

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Detalles Bibliográficos
Autores principales: Occhipinti, Giovanni, Nascimento, Daniel L., Foscato, Marco, Fogg, Deryn E., Jensen, Vidar R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9093171/
https://www.ncbi.nlm.nih.gov/pubmed/35655574
http://dx.doi.org/10.1039/d2sc00855f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9093171/
https://www.ncbi.nlm.nih.gov/pubmed/35655574
http://dx.doi.org/10.1039/d2sc00855f

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