Cargando…
[Ni(30)S(16)(PEt(3))(11)]: an open-shell nickel sulfide nanocluster with a “metal-like” core
Reaction of [Ni(1,5-cod)(2)] (30 equiv.) with PEt(3) (46 equiv.) and S(8) (1.9 equiv.) in toluene, followed by heating at 115 °C for 16 h, results in the formation of the atomically precise nanocluster (APNC), [Ni(30)S(16)(PEt(3))(11)] (1), in 14% isolated yield. Complex 1 represents the largest ope...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9093199/ https://www.ncbi.nlm.nih.gov/pubmed/35655571 http://dx.doi.org/10.1039/d2sc00960a |