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Cation Disorder and Large Tetragonal Supercell Ordering in the Li-Rich Argyrodite Li(7)Zn(0.5)SiS(6)
[Image: see text] A tetragonal argyrodite with >7 mobile cations, Li(7)Zn(0.5)SiS(6), is experimentally realized for the first time through solid state synthesis and exploration of the Li–Zn–Si–S phase diagram. The crystal structure of Li(7)Zn(0.5)SiS(6) was solved ab initio from high-resolution...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9097155/ https://www.ncbi.nlm.nih.gov/pubmed/35573111 http://dx.doi.org/10.1021/acs.chemmater.2c00320 |