Nucleophilic Fluorination Catalyzed by a Cyclometallated Rhodium Complex

[Image: see text] Quantitative catalytic nucleophilic fluorination of a range of acyl chlorides to acyl fluorides was promoted by a cyclometallated rhodium complex [(η(5),κ(2)C-C(5)Me(4)CH(2)C(6)F(5)CH(2)NC(3)H(2)NMe)- RhCl] (1). 1 can be prepared in high yields from commercially available starting...

Descripción completa

Detalles Bibliográficos
Autores principales: Morgan, Patrick J., Saunders, Graham C., Macgregor, Stuart A., Marr, Andrew C., Licence, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9098193/
https://www.ncbi.nlm.nih.gov/pubmed/35571260
http://dx.doi.org/10.1021/acs.organomet.2c00052

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9098193/
https://www.ncbi.nlm.nih.gov/pubmed/35571260
http://dx.doi.org/10.1021/acs.organomet.2c00052

Ejemplares similares