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Nucleophilic Fluorination Catalyzed by a Cyclometallated Rhodium Complex
[Image: see text] Quantitative catalytic nucleophilic fluorination of a range of acyl chlorides to acyl fluorides was promoted by a cyclometallated rhodium complex [(η(5),κ(2)C-C(5)Me(4)CH(2)C(6)F(5)CH(2)NC(3)H(2)NMe)- RhCl] (1). 1 can be prepared in high yields from commercially available starting...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9098193/ https://www.ncbi.nlm.nih.gov/pubmed/35571260 http://dx.doi.org/10.1021/acs.organomet.2c00052 |