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Missing Link in the Growth of Lead-Based Zintl Clusters: Isolation of the Dimeric Plumbaspherene [Cu(4)Pb(22)](4–)
[Image: see text] We report here the structure of an endohedral plumbaspherene, [Cu(4)Pb(22)](4–), the gold analogue of which was previously postulated to be a “missing link” in the growth of larger clusters containing three and four icosahedral subunits. The cluster contains two [Cu(2)Pb(11)](2–) s...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9100666/ https://www.ncbi.nlm.nih.gov/pubmed/35451815 http://dx.doi.org/10.1021/jacs.1c10106 |