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Missing Link in the Growth of Lead-Based Zintl Clusters: Isolation of the Dimeric Plumbaspherene [Cu(4)Pb(22)](4–)

[Image: see text] We report here the structure of an endohedral plumbaspherene, [Cu(4)Pb(22)](4–), the gold analogue of which was previously postulated to be a “missing link” in the growth of larger clusters containing three and four icosahedral subunits. The cluster contains two [Cu(2)Pb(11)](2–) s...

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Detalles Bibliográficos
Autores principales: Morgan, Harry W. T., Shu, Cong-Cong, Sun, Zhong-Ming, McGrady, John E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9100666/
https://www.ncbi.nlm.nih.gov/pubmed/35451815
http://dx.doi.org/10.1021/jacs.1c10106