Insight into Spodium–π Bonding Characteristics of the MX(2)⋯π (M = Zn, Cd and Hg; X = Cl, Br and I) Complexes—A Theoretical Study

The spodium–π bonding between MX(2) (M = Zn, Cd, and Hg; X = Cl, Br, and I) acting as a Lewis acid, and C(2)H(2)/C(2)H(4) acting as a Lewis base was studied by ab initio calculations. Two types of structures of cross (T) and parallel (P) forms are obtained. For the T form, the X–M–X axis adopts a cr...

Descripción completa

Detalles Bibliográficos
Autores principales: Gao, Meng, Zhao, Qibo, Yu, Hao, Fu, Min, Li, Qingzhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9101229/
https://www.ncbi.nlm.nih.gov/pubmed/35566234
http://dx.doi.org/10.3390/molecules27092885

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9101229/
https://www.ncbi.nlm.nih.gov/pubmed/35566234
http://dx.doi.org/10.3390/molecules27092885

Ejemplares similares