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Insight into Spodium–π Bonding Characteristics of the MX(2)⋯π (M = Zn, Cd and Hg; X = Cl, Br and I) Complexes—A Theoretical Study
The spodium–π bonding between MX(2) (M = Zn, Cd, and Hg; X = Cl, Br, and I) acting as a Lewis acid, and C(2)H(2)/C(2)H(4) acting as a Lewis base was studied by ab initio calculations. Two types of structures of cross (T) and parallel (P) forms are obtained. For the T form, the X–M–X axis adopts a cr...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9101229/ https://www.ncbi.nlm.nih.gov/pubmed/35566234 http://dx.doi.org/10.3390/molecules27092885 |