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Organophotoredox-catalyzed semipinacol rearrangement via radical-polar crossover
Over the past century, significant progress in semipinacol rearrangement involving 1,2-migration of α-hydroxy carbocations has been made in the areas of catalysis and total synthesis of natural products. To access the α-hydroxy carbocation intermediate, conventional acid-mediated or electrochemical...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9106707/ https://www.ncbi.nlm.nih.gov/pubmed/35562383 http://dx.doi.org/10.1038/s41467-022-30395-4 |