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Synthesis of enol phosphates directly from ketones via a modified one-pot Perkow reaction

A modified Perkow reaction, named Perkow-Shi reaction, was developed based on the one-pot α-tosyloxylation of ketones following by addition of P(iii)-reagents and 4 Å molecular sieves. Diversity of enol phosphates, as well as enol phosphonates, enol phosphinates, and enol phosphoramidates were synth...

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Detalles Bibliográficos
Autores principales: Guo, Huichuang, Zhang, Yulong, Li, Zhenya, Zhao, Peichao, Li, Ning, Shi, Enxue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9112406/
https://www.ncbi.nlm.nih.gov/pubmed/35702246
http://dx.doi.org/10.1039/d2ra02340g